Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide.
Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide.
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DOI：
10.1021/ic7014995
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发表时间：
2007-09
影响因子：
4.6
通讯作者：
H. Yoo;Jae Il Kim;N. Yang;E. Koh;Je-Guen Park;C. Hong
中科院分区：
文献类型：
--
作者：
H. Yoo;Jae Il Kim;N. Yang;E. Koh;Je-Guen Park;C. Hong
通过自组装方法合成了一种新型一维手性配位聚合物[Co（bmdt）（N3）2].MeCN（1.MeCN）。磁性数据表明，通过单一的端到端的叠氮基链内的铁磁耦合进行观察，这是一个不寻常的情况下，叠氮桥钴（II）系统。
A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2].MeCN (1.MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.