Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution.
Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution.
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DOI：
10.1039/c1cc14591f
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发表时间：
2011-09
影响因子：
4.9
通讯作者：
Bin Hu;M. Meng;J. Fossey;W. Mo;Xinquan Hu;W. Deng
中科院分区：
文献类型：
--
作者：
Bin Hu;M. Meng;J. Fossey;W. Mo;Xinquan Hu;W. Deng
Planar chiral nucleophilic catalyst Fc-PIP was employed in the kinetic resolution of bulky (hetero)arylalkyl carbinols delivering unreacted alcohols with extremely high enantiomeric excess (>99.0% ees) in ideal conversions ranging from 50.4-56.7%.
