Functional group-selective poisoning of molecular catalysts: a ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters.
Functional group-selective poisoning of molecular catalysts: a ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters.
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DOI：
10.1039/b711743d
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发表时间：
2007-11
影响因子：
4.9
通讯作者：
Hidehiro Sasakuma;Yukihiro Motoyama;H. Nagashima
中科院分区：
文献类型：
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作者：
Hidehiro Sasakuma;Yukihiro Motoyama;H. Nagashima
胺的加入消除了三钌簇在酮和酯的氢化硅烷还原中的催化活性，而不影响酰胺的还原速率;完成了酰胺基酮和酰胺基酯中的酰胺基团的选择性还原。
The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.