Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides
Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides
复制标题
两种席夫碱和卤化物叠氮桥双核锌(II)配合物的合成和晶体结构
DOI:
10.1080/15533174.2011.609503
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发表时间:
2012
期刊:
影响因子:
--
通讯作者:
Z. You
中科院分区:
文献类型:
--
作者:
R. Hui;P. Zhou;Z. You
Two end-on azide-bridged dinuclear Schiff base zinc(II) complexes, [Zn2Br2(μ1,1-N3)L1 2]·H2O (1) and [Zn2I2(μ1,1-N3)L2 2]·I (2) (L1 = 4-bromo-2-[(2-isopropylaminoethylimino)methyl]phenol, L2 = 2-ethoxy-6-[(2-ethylaminoethylimino)methyl]phenol), have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. One Zn atom in (1) is five-coordinated in a square pyramidal geometry, while the other Zn atom in (1) and the Zn atoms in (2) are in tetrahedral geometries.