Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides

Syntheses and Crystal Structures of Two Azide-Bridged Dinuclear Zinc(II) Complexes with Schiff Bases and Halides
复制标题

两种席夫碱和卤化物叠氮桥双核锌(II)配合物的合成和晶体结构

DOI:
10.1080/15533174.2011.609503
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发表时间:
2012
期刊:
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
影响因子:
--
通讯作者:
Z. You
Z. You
中科院分区:
--
文献类型:
--
作者:
R. Hui;P. Zhou;Z. You

文献摘要

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两个端叠氮桥联双核Schiff碱锌配合物[Zn 2Br 2(μ 1,1-N3)L1 2]·H2O(1)和[Zn 2 I2(μ 1,1-N3)L2 2]·I(2)(L1 = 4-溴-2-[(2-异丙基氨基乙基亚氨基)甲基]苯酚,L2 = 2-乙氧基-6-[合成了一种新的含2-(2-乙氨基乙基亚氨基)甲基]苯酚的配合物,并通过元素分析、红外光谱和X-射线单晶衍射对其结构进行了表征。(1)中的一个Zn原子为五配位的四方锥构型,而(1)中的另一个Zn原子和(2)中的Zn原子为四面体构型。
Two end-on azide-bridged dinuclear Schiff base zinc(II) complexes, [Zn2Br2(μ1,1-N3)L1 2]·H2O (1) and [Zn2I2(μ1,1-N3)L2 2]·I (2) (L1 = 4-bromo-2-[(2-isopropylaminoethylimino)methyl]phenol, L2 = 2-ethoxy-6-[(2-ethylaminoethylimino)methyl]phenol), have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. One Zn atom in (1) is five-coordinated in a square pyramidal geometry, while the other Zn atom in (1) and the Zn atoms in (2) are in tetrahedral geometries.