Nonlinear Block Copolymer Architectures

Nonlinear Block Copolymer Architectures
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DOI:
10.1007/3-540-69191-x_1
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发表时间:
1998
影响因子:
--
通讯作者:
M. Pitsikalis;S. Pispas;J. Mays;N. Hadjichristidis
M. Pitsikalis;S. Pispas;J. Mays;N. Hadjichristidis
中科院分区:
化学4区
文献类型:
--
作者:
M. Pitsikalis;S. Pispas;J. Mays;N. Hadjichristidis

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综述了具有非线性结构的嵌段共聚物的合成以及本体和溶液性质。这些材料包括星形嵌段共聚物、接枝共聚物、miktoarm星形共聚物以及复杂的结构,例如伞形聚合物和某些树枝状大分子。重点放在定义明确、特征明确的材料的合成上。此类聚合物可作为模型材料,用于了解结构对本体和溶液中嵌段共聚物自组装的影响。
The synthesis and bulk and solution properties of block copolymers having nonlinear architectures are reviewed. These materials include star-block copolymers, graft copolymers, miktoarm star copolymers, and complex architectures such as umbrella polymers and certain dendritic macromolecules. Emphasis is placed on the synthesis of well-defined, well-characterized materials. Such polymers serve as model materials for understanding the effects of architecture on block copolymer self-assembly, in bulk and in solution.