Radical addition to "Cation pool". Reverse process of radical cation fragmentation
Radical addition to "Cation pool". Reverse process of radical cation fragmentation
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DOI：
10.1021/ja0511218
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发表时间：
2005-05-25
影响因子：
15
通讯作者：
Yoshida, JI
中科院分区：
文献类型：
--
作者：
Maruyama, T;Suga, S;Yoshida, JI
ANN-酰亚胺离子与烷基碘和六丁基杂环己烷反应生成烷基化产物。提出了一种将烷基自由基加成到酰亚胺离子上，生成相应的自由基阳离子的机理。
The reaction of anN-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to anN-acyliminium ion to produce the corresponding radical cation has been suggested.