Carbon-Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand
Carbon-Carbon Bond Forming Reactions Promoted by Aluminyl and Alumoxane Anions: Introducing the Ethenetetraolate Ligand
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铝基和铝氧烷阴离子促进的碳-碳键形成反应：引入乙烯四醇盐配体
DOI：
10.1002/ange.202005301
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发表时间：
2020
影响因子：
--
通讯作者：
Anker M
中科院分区：
文献类型：
--
作者：
Anker M
[K{Al(NONDipp)}]2(NONDipp=[O(SiMe2NDipp)2]2−, Dipp=2,6‐iPr2C6H3) reacts with CS2to afford the trithiocarbonate species [K(OEt2)][Al(NONDipp)(CS3)]1or the ethenetetrathiolate complex, [K{Al(NONDipp)(S2C)}]2[3]2. The dimeric alumoxane [K{Al(NONDipp)(O)}]2reacts with carbon monoxide to afford the oxygen analogue of3, [K{Al(NONDipp)(O2C)}]2[4]2containing the hitherto unknown ethenetetraolate ligand, [C2O4]4−.
