Skeleton-selective fluorescent chemosensor based on cyclodextrin bearing a 4-amino-7-nitrobenz-2-oxa-1,3-diazole moiety.

Skeleton-selective fluorescent chemosensor based on cyclodextrin bearing a 4-amino-7-nitrobenz-2-oxa-1,3-diazole moiety.
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基于带有 4-氨基-7-硝基苯甲-2-氧杂-1,3-二唑部分的环糊精的骨架选择性荧光化学传感器。

DOI:
10.1039/b508477f
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发表时间:
2005
影响因子:
3.2
通讯作者:
A. Ueno
A. Ueno
中科院分区:
化学3区
文献类型:
--
作者:
H. Ikeda;Takuya Murayama;A. Ueno

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A new type of fluorescent chemosensor, based on modified cyclodextrins bearing the fluorophore unit NBD-amine, was prepared. One of these new chemosensors, NC0betaCD, is sensitive to adamantane and borneol derivatives, which have a comparatively spherical shape that fits the beta-CD cavity, but is not sensitive to bile acids, which are strongly bound by the native beta-CD. Even in the presence of a bile acid, NC0betaCD can detect 1-adamantanol. Another of this new type of chemosensors, NC0gammaCD, is sensitive to bile acids but not to adamantane derivatives. The response of the new type of chemosensors to a guest was an increase in the fluorescence intensity.
DOI: 10.1038/356136a0
发表时间: 1992-03-12
期刊: NATURE
影响因子: 64.8
作者:
UENO, A;KUWABARA, T;TODA, F
通讯作者: TODA, F