Soluble Conjugated Microporous Polymers
Soluble Conjugated Microporous Polymers
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DOI：
10.1002/anie.201205521
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发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Cooper, Andrew I.
中科院分区：
文献类型：
--
作者：
Cheng, Ge;Hasell, Tom;Cooper, Andrew I.
可溶性和多孔性：可溶共轭微孔聚合物（SCMPs）可以通过合成离散的超支化分子来制备。这种材料可以从溶液中铸造成薄膜（见图），这表明了一系列不溶性CMP网络所没有的加工选择。可溶性，共轭树突状物是多孔的，并提供洞察微孔隙的结构起源。
Soluble and porous: Soluble conjugated microporous polymers (SCMPs) can be prepared by synthesizing discrete hyperbranched molecules. The materials can be cast from solution as thin films (see picture), suggesting a range of processing options that are not available for insoluble CMP networks. Soluble, conjugated dendrimers are porous and give insight into the structural origin of microporosity.