A Stable and Crystalline Triarylgermyl Radical: Structure and EPR Spectra
A Stable and Crystalline Triarylgermyl Radical: Structure and EPR Spectra
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DOI：
10.1002/anie.200805328
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Reinhold, Joachim
中科院分区：
文献类型：
--
作者：
Drost, Christian;Griebel, Jan;Reinhold, Joachim
一个激进的东西：在以低产率意外获得后，第一个稳定的三芳基甲锗烷基自由基Ge[3,5-tBu2-2,6-(EtO)2C6H]3(1; C gray, O blue)的合成得到了显着优化，并通过X射线分析和EPR光谱对产物进行了研究。结果与模型化合物 Ge[2,6-(MeO)2C6H3] 的 DFT-MO 研究进行了比较。
A radical thing: After being obtained unexpectedly in low yields, the synthesis of the first stable triarylgermyl radical.Ge[3,5‐tBu2‐2,6‐(EtO)2C6H]3(1; C gray, O blue) was considerably optimized, and the product was investigated by X‐ray analysis and EPR spectroscopy. The results were compared with DFT‐MO studies for the model compound.Ge[2,6‐(MeO)2C6H3].