Uranium triamidoamine chemistry
Uranium triamidoamine chemistry
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DOI：
10.1039/c5cc01360g
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发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Liddle, Stephen T.
中科院分区：
文献类型：
--
作者：
Gardner, Benedict M.;Liddle, Stephen T.
p-和d-区元素的三酰胺胺（Tren）配合物已经得到了很好的研究，它们显示出各种各样的学术，工业和生物学意义的化学。尽管由于铀在核部门的基本地位，人们普遍希望更好地了解铀的化学行为，但对铀的特伦络合物的这种深入调查并不普遍。然而，Tren-铀络合物的化学特征在于稳定否则反应性的、多键合的主基团供体原子配体、构建铀-金属键、促进小分子活化和支持单分子磁性的能力，所有这些都利用了Tren配体系统的空间、电子、热力学和动力学特征。这篇专题文章介绍了Tren铀络合物化学的最新进展。
Triamidoamine (Tren) complexes of the p- and d-block elements have been well-studied, and they display a diverse array of chemistry of academic, industrial and biological significance. Such in-depth investigations are not as widespread for Tren complexes of uranium, despite the general drive to better understand the chemical behaviour of uranium by virtue of its fundamental position within the nuclear sector. However, the chemistry of Tren-uranium complexes is characterised by the ability to stabilise otherwise reactive, multiply bonded main group donor atom ligands, construct uranium-metal bonds, promote small molecule activation, and support single molecule magnetism, all of which exploit the steric, electronic, thermodynamic and kinetic features of the Tren ligand system. This Feature Article presents a current account of the chemistry of Tren-uranium complexes.