Metal oxo complexes as catalysts for the isomerisation of allylic alcohols
Metal oxo complexes as catalysts for the isomerisation of allylic alcohols
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DOI：
10.1016/s1631-0748(02)01371-1
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发表时间：
2002-04-01
影响因子：
1.6
通讯作者：
Le Ny, JP
中科院分区：
文献类型：
--
作者：
Bellemin-Laponnaz, S;Le Ny, JP
烯丙醇的1,3-烯丙基重排是有机合成中的重要转化，并且已经报道了实现这种转座的各种方法。这篇简短的综述将重点关注作为烯丙醇异构化催化剂的过渡金属氧配合物的开发。还讨论了机理研究。 (C) 2002 年科学院 / 科学与医学版 Elsevier SAS。
The 1,3-allylic rearrangement of allylic alcohols is an important transformation in organic synthesis and various methods for effecting such a transposition have been reported. This short review will focus on the development of transition metal oxo complexes as catalysts for the isomerisation of allylic alcohols. Mechanistic investigations are also discussed. (C) 2002 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.