A Facile High-Yield Synthesis and Purification of Tetrabutylammonium Tetrabutylborate.
A Facile High-Yield Synthesis and Purification of Tetrabutylammonium Tetrabutylborate.
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四丁基硼酸四丁基铵的简便高产率合成和纯化。
DOI：
10.1021/jo971506b
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发表时间：
1998
期刊：
影响因子：
--
通讯作者：
Hengge,AlvanC.
中科院分区：
文献类型：
--
作者：
Hoff,RichardH.;Hengge,AlvanC.
化合物四丁基硼酸四丁基铵在几个化学领域有很长的使用历史，1特别是在离子溶剂化热力学的研究中。2直到最近，这种化合物还在商业上可以买到，尽管来源单一。目前还没有四丁基硼酸四丁基铵的商业来源。我们的文献检索只发现了一种单一的低产率(3此外，报道了其提纯困难，文献中纯化合物的熔点范围从109.5 C4到110.6−112.0 C.3
The compound tetrabutylammonium tetrabutylborate has a long history of use in several areas of chemistry, 1 and particularly in studies of the thermodynamics of ion solvation. 2 Until very recently this compound was commercially available, albeit from a single source. Presently there are no commercial sources for tetrabutylammonium tetrabutylborate. Our search of the literature turned up only a single, low-yield (3 In addition difficulties in its purification have been reported, and literature melting points for the pure compound range from 109.5 C 4 to 110.6− 112.0 C. 3