Facile synthesis of an organically-derivatized hexavanadate containing the remote amino group, TBA2[V6O13{(OCH2)3CNH2}2]
Facile synthesis of an organically-derivatized hexavanadate containing the remote amino group, TBA2[V6O13{(OCH2)3CNH2}2]
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轻松合成含有远程氨基的有机衍生六钒酸盐 TBA(2)[V6O13{(OCH2)(3)CNH2}(2)]
DOI：
10.1039/c5ce02534f
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发表时间：
2016-01-01
期刊：
影响因子：
3.1
通讯作者：
Wei, Yongge
中科院分区：
文献类型：
--
作者：
Bayaguud, Aruuhan;Chen, Kun;Wei, Yongge
提出了一种有效的合成含氨基六钒酸盐有机衍生物TBA（2）[V6O 13 {（OCH 2）（3）CNH 2}（2）]的方法。该方法大大提高了产率，得到了中间体和阳离子交换产物的晶体，并通过单晶X射线衍射、IR和1H-1NMR对其结构进行了表征。
An effective synthetic strategy for the amino-containing organic derivative of hexavanadate, TBA(2)[V6O13{(OCH2)(3)CNH2}(2)], is presented. By using this method, the yield is increased extremely and crystals of the intermediate and cation-exchanged products are both obtained and structurally characterized via single-crystal X-ray diffraction, IR and H-1-NMR.