HIPed Tailored Pyrochlore-Rich Glass-Ceramic Waste Forms for the Immobilization of Nuclear Waste

HIPed Tailored Pyrochlore-Rich Glass-Ceramic Waste Forms for the Immobilization of Nuclear Waste
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用于固定核废料的 HIPed 定制富含烧绿石的玻璃陶瓷废料形式

DOI:
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发表时间:
2008
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通讯作者:
E. Vance
E. Vance
中科院分区:
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文献类型:
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作者:
M. Carter;Hui Li;Yingjie Zhang;A. Gillen;E. Vance

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设计了热等静压(HIPed)微晶玻璃用于固定化富铀中级废物和汉福德k池污泥。这些是基于玻璃中焦绿结构的Ca (1-x) U (1+y) Ti 2 O 7,以及少量的结晶相。对选定的玻璃陶瓷样品进行了详细的微观结构、衍射和光谱表征,通过mc1和PCT-B浸出试验测量,化学耐久性是足够的。
Hot isostatically pressed (HIPed) glass-ceramics for the immobilization of uranium-rich intermediate-level wastes and Hanford K-basin sludges were designed. These were based on pyrochlore-structured Ca (1-x) U (1+y) Ti 2 O 7 in glass, together with minor crystalline phases. Detailed microstructural, diffraction and spectroscopic characterization of selected glass-ceramic samples has been performed, and chemical durability is adequate, as measured by both MCC-1 and PCT-B leach tests.