2D-grid layered Pd-based cationic infinite coordination polymer/polyoxometalate crystal with hydrophilic sorption.
2D-grid layered Pd-based cationic infinite coordination polymer/polyoxometalate crystal with hydrophilic sorption.
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DOI：
10.1021/ic061393r
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发表时间：
2006-10
影响因子：
4.6
通讯作者：
Kazuhiro Uehara;Hideaki Nakao;Ryosuke Kawamoto;S. Hikichi;N. Mizuno
中科院分区：
文献类型：
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作者：
Kazuhiro Uehara;Hideaki Nakao;Ryosuke Kawamoto;S. Hikichi;N. Mizuno
本发明的新型无限链Pd（II）配合物与聚氧乙烯酸盐（{[（en）Pd（p-bpy）]2[alpha-SiW 12 O 40]·8DMSO·4DMF}infinity）组成的无机-有机杂化化合物，（1a：1与8DMSO.4DMF;单斜晶系P2（1）/c（No.14），a = 15.0188（3）A，B = 15.6962（3）A，c = 26.9793（6）A，β = 106.3580（10）度，V = 6102.6（2）A（3））。在50 ℃下在干燥N（2）中处理或在室温下抽真空形成{[（en）Pd（p-bpy）]（2）[alpha-SiW（12）O（40）].6.0DMSO}（无穷大）（1b：1与6DMSO），层间距急剧减小，这通过粉末衍射分析和1c的单晶分析来表征（1与4.5DMSO·3.5DMF;单斜P2（1）/a（No.14），a = 14.200（9）A，B = 22.8865（8）A，c = 14.8558（5）A，β = 114.7990（10）度，V = 4383.0（2）A（3））。化合物1b可逆地吸附的亲水性分子的内在结构的维护，这是非常不同的疏水性客人包合物的性质，在其他钯基超分子系统中报道。
The inorganic-organic hybrid compound composed of the novel infinite-chain Pd(II) complex and the polyoxometalate ({[(en)Pd(p-bpy)]2[alpha-SiW12O40].8DMSO.4DMF}infinity (1a:1 with 8DMSO.4DMF; monoclinic P2(1)/c (No. 14), a = 15.0188(3) A, b = 15.6962(3) A, c = 26.9793(6) A, beta = 106.3580(10) degrees , V = 6102.6(2) A(3)) has been successfully synthesized by the reaction of [(en)Pd(OH2)2]2[alpha-SiW12O40] (2) with 4,4'-bipyridine (p-bpy). The treatment in dry N(2) at 50 degrees C or evacuation at room temperature forms {[(en)Pd(p-bpy)](2)[alpha-SiW(12)O(40)].6.0DMSO}(infinity) (1b:1 with 6DMSO) with a drastic reduction of the interlayer spacing, which is characterized by the powder diffraction analysis and the single-crystal analysis of 1c (1 with 4.5DMSO.3.5DMF; monoclinic P2(1)/a (No. 14), a = 14.200(9) A, b = 22.8865(8) A, c = 14.8558(5) A, beta = 114.7990(10) degrees , V = 4383.0(2) A(3)). Compound 1b reversibly sorbs the hydrophilic molecules with the maintenance of the intrinsic structure, which is much different from hydrophobic guest-inclusion properties reported in the other Pd-based supramolecular systems.