Effect of benzoic acid on the removal of 1,2-dichloroethane by a siderite-catalyzed hydrogen peroxide and persulfate system

Effect of benzoic acid on the removal of 1,2-dichloroethane by a siderite-catalyzed hydrogen peroxide and persulfate system
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苯甲酸对菱铁矿催化过氧化氢和过硫酸盐体系去除1,2-二氯乙烷的影响

DOI:
10.1007/s11356-015-5124-0
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发表时间:
2016-01-01
影响因子:
5.8
通讯作者:
Chen, Honghan
Chen, Honghan
中科院分区:
环境科学与生态学3区
文献类型:
--
作者:
Li, Shengpin;Li, Mengjiao;Chen, Honghan

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Benzoic acid can affect the iron-oxide mineral dissolution and react with hydroxyl radical. This study investigated its effect on 1,2-dichloroethane removal process by siderite-catalyzed hydrogen peroxide and persulfate. The variation of benzoic acid concentrations can affect pH value and soluble iron concentrations; when benzoic acid varied from 0 to 0.5 mmol/L, pH increased while Fe(2+) and Fe(3+) concentrations decreased, resulting in 1,2-dichloroethane removal efficiency which decreased from 91.2 to 5.0%. However, when benzoic acid varied from 0.5 to 10 mmol/L, pH decreased while Fe(2+) and Fe(3+) concentrations increased, resulting in 1,2-dichloroethane removal efficiency which increased from 5.0 to 83.4%.