Structure of two encapsulated cobalt(III) complexes containing cyclo-triphosphate

Structure of two encapsulated cobalt(III) complexes containing cyclo-triphosphate
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两种含有环三磷酸盐的封装钴(III)配合物的结构

DOI:
10.1107/s0108270193004263
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发表时间:
1993
期刊:
Acta Crystallographica Section C-crystal Structure Communications
影响因子:
--
通讯作者:
G. Pelizzi
G. Pelizzi
中科院分区:
--
文献类型:
--
作者:
A. Bacchi;F. Ferranti;G. Pelizzi

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研究了两种含环三磷酸酯的钴(III)配合物的构象和堆积性质。化合物(I),(1,3,6,8,10,13,16,19-八氮杂双环[6.6.6]二十烷)钴(III)环三磷酸盐-水(2/7)具有俗名钴(III)分离环三磷酸盐-水(2/7)和化学式[Co(sep)](P3 O 9).3.5H2O。阳离子显示出与其他sepulchrate络合物中发现的非常相似的LEL 3几何构型
The conformational and packing properties of two encapsulated cobalt(III) complexes containing cyclo-triphosphate have been investigated. Compound (I), (1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]icosane)cobalt(III) cyclo-triphosphate-water (2/7) has the trivial name cobalt(III) sepulchrate cyclo-triphosphate-water (2/7) and chemical formula [Co(sep)](P 3 O 9 ).3.5H 2 O. The cation shows an lel 3 geometry very similar to those found in other sepulchrate complexes