Alkylation of Phenols by Oxidation-Reduction Condensation Using 2,6-Dimethyl-1,4-benzoquinone and Alkoxydiphenylphosphine
Alkylation of Phenols by Oxidation-Reduction Condensation Using 2,6-Dimethyl-1,4-benzoquinone and Alkoxydiphenylphosphine
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使用 2,6-二甲基-1,4-苯醌和烷氧基二苯基膦通过氧化还原缩合对苯酚进行烷基化
DOI：
10.1246/cl.2003.22
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发表时间：
2003
影响因子：
1.6
通讯作者：
T. Mukaiyama
中科院分区：
文献类型：
--
作者：
Taichi Shintou;Wataru Kikuchi;T. Mukaiyama
以氯二苯基膦和相应的醇为原料，在温和的条件下，与多种酚在2,6-二甲基-1,4-苯醌（DMBQ）共存的条件下，以氧化还原缩合的方法制备了多种烷基苯基醚，收率高。
Various alkyl phenyl ethers were obtained in high yields by way of oxidation-reduction condensation where alkoxydiphenylphosphine, prepared easily from chlorodiphenylphosphine and corresponding alcohols, was treated with various phenols in the co-existence of 2,6-dimethyl-1,4-benzoquinone(DMBQ) under mild conditions.