MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure
MX-type single chain complexes with an aromatic in-plane ligand: incorporation of aromatic interactions for stabilizing the chain structure
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具有芳香族面内配体的 MX 型单链配合物：引入芳香族相互作用以稳定链结构
DOI：
10.1039/c9dt00784a
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发表时间：
2019
影响因子：
4
通讯作者：
Yamashita Masahiro
中科院分区：
文献类型：
--
作者：
Afrin Unjila;Iguchi Hiroaki;Mian Mohammad Rasel;Takaishi Shinya;Yamakawa Hiromichi;Terashige Tsubasa;Miyamoto Tatsuya;Okamoto Hiroshi;Yamashita Masahiro
合成了MX型一维配合物[PtIV（amp）2Br 2][PtII/IV（amp）2Br]2（HSO 4）2（SO 4）2·13 H2O（3）和[PtIV（amp）2Br 2][PtII/IV（amp）2Br]2（H2 PO 4）6·8H 2 O（4）。化合物3和4的Pt-Br链结构是通过链上沿着的氢键网络和插层Pt（IV）配合物的π堆积来稳定的。结构和光谱研究表明，3和4形成Pt（II/IV）混合价态。
MX-type one-dimensional complexes [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(HSO4)2(SO4)2·13H2O (3) and [PtIV(amp)2Br2][PtII/IV(amp)2Br]2(H2PO4)6·8H2O (4) were synthesized as the first analogue containing only an aromatic in-plane ligand. The Pt–Br chain structures of 3 and 4 are stabilized by both the hydrogen-bond network along the chain and the π-stacking via intercalated Pt(IV) complexes. Structural and spectroscopic studies indicated that both 3 and 4 form the Pt(II/IV) mixed valence state.