Arylamide dendrimers with flexible linkers via haloacyl halide method.
Arylamide dendrimers with flexible linkers via haloacyl halide method.
复制标题
通过卤代酰卤方法具有柔性连接基的芳酰胺树枝状聚合物。
DOI：
10.1021/ol050341n
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发表时间：
2005
期刊：
影响因子：
5.2
通讯作者：
Vinogradov,SergeiA
中科院分区：
文献类型：
--
作者：
Vinogradov,SergeiA
Soluble arylamide dendrons with flexible linkers, peripheral ester or carboxyl groups (R), and focal amino or halogen functionalities (F) were synthesized from aryl glycineamide (AG) building blocks. The AG blocks were prepared in high yields from trivial starting materials by Fischer's haloacyl halide method, which also could be extended to the dendrimer synthesis itself. The G2 AG dendrons were coupled to a Pd porphyrin core, demonstrating outstanding encapsulation efficiency in aqueous solutions.
