A photocatalytic sp3 C-S, C-Se and C-B bond formation through C-C bond cleavage of cycloketone oxime esters
A photocatalytic sp3 C-S, C-Se and C-B bond formation through C-C bond cleavage of cycloketone oxime esters
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通过环酮肟酯的C-C键断裂形成光催化sp3 C-S、C-Se和C-B键
DOI：
10.1039/c8ob02987c
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发表时间：
2019-01-21
影响因子：
3.2
通讯作者：
Zhou, Lei
中科院分区：
文献类型：
--
作者：
Anand, Devireddy;He, Yuwei;Zhou, Lei
描述了通过亚氨基自由基引发的 C-C 键断裂对环酮肟酯进行光催化硫醇化、硒化和硼化。这些反应为合成与合成有用的腈基团相连的烷基硫、硒和硼化合物提供了统一的方法。
The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C-C bond cleavage were described. The reactions provide a unified approach to alkyl sulfur, selenium and boron compounds tethered to a synthetically useful nitrile group.