Anomalous anthracene arrangement and rare excimer emission in the solid state: Transcription and translation of molecular information

Anomalous anthracene arrangement and rare excimer emission in the solid state: Transcription and translation of molecular information
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DOI:
10.1021/ol0616440
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发表时间:
2006-09-14
期刊:
影响因子:
5.2
通讯作者:
Tohnai, Norimitsu
Tohnai, Norimitsu
中科院分区:
化学1区
文献类型:
--
作者:
Mizobe, Yuji;Miyata, Mikiji;Tohnai, Norimitsu

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通过利用三元系统获得了蒽部分的新颖分子排列和相应的稀有固态准分子发射。该系统由蒽二磺酸铵和加合物组成,并显示出根据加合物对固态发射模式的调节。加合物充当被转录为排列的分子信息源,并且排列被转化为发射模式。这一系列的过程可能是对中心法则的模仿。
A novel molecular arrangement of anthracene moieties and the corresponding rare solid-state excimer emission is obtained by utilization of a ternary system. The system consists of ammonium anthracene disulfonate and adducts, and shows the modulation of the solid-state emission mode depending on the adducts. The adducts act as molecular information sources that are transcribed to the arrangement, and the arrangement is translated into the emission mode. This series of processes might be mimicry of central dogma.