Recombination profiles in poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] light-emitting electrochemical cells
Recombination profiles in poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] light-emitting electrochemical cells
复制标题
聚[2-甲氧基-5-(2-乙基己氧基)-1,4-亚苯基亚乙烯基]发光电化学电池中的重组谱
DOI：
10.1063/1.2149162
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发表时间：
2005
影响因子：
3.2
通讯作者：
B. Ruhstaller
中科院分区：
文献类型：
--
作者：
J. Léger;S. Carter;B. Ruhstaller
本文研究了基于聚[2-甲氧基-5-（2-乙基己氧基）-1,4-苯基乙烯基]（MEH-PPV）的发光电化学电池（LECs）的光学和电子特性，目的是了解其发射谱图并表征其对盐和电极的依赖性。为了深入了解垂直结构LECs的发光特征，对平面LECs的光致发光和电致发光进行了直接成像，并模拟了光干涉效应。虽然我们的结果与氧化掺杂一致，但它们意味着在正常操作条件下LECs缺乏还原性掺杂。我们观察到发射曲线的趋势与厚度、盐和电极类型无关。此外，测量了器件电流-电压（I-V）和辐射特性作为盐和电极类型的函数。对于Al vs .的器件，观察到I-V特性、导通电压和整流的变化。Au触点和具有各种…
We present a study on the optical and electronic properties of light-emitting electrochemical cells (LECs) based on poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) with the goal of understanding emission profiles and characterizing salt and electrode dependence. Direct imaging of photoluminescence and electroluminescence profiles of planar LECs and simulations of optical interference effects were performed in order to gain insight into emission profiles in vertical structure LECs. While our results are consistent with oxidative doping, they imply a lack of reductive doping in LECs under normal operating conditions. We observe that trends in emission profiles are independent of thickness, salt, and electrode type. In addition, device current-voltage (I-V) and radiance characteristics were measured as a function of salt and electrode type. Variations in the I-V characteristics, turn-on voltage, and rectification are observed for devices with Al versus. Au contacts and for salts with vari...