Evidence for Electron-transfer Process in Abnormal Grignard Reactions. Enolization and α-Diketone Formation
Evidence for Electron-transfer Process in Abnormal Grignard Reactions. Enolization and α-Diketone Formation
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异常格氏反应中电子转移过程的证据。
DOI：
10.1246/bcsj.53.3029
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发表时间：
1980
期刊：
影响因子：
--
通讯作者：
R. Suenaga
中科院分区：
文献类型：
--
作者：
M. Ōkubo;Y. Morigami;R. Suenaga
研究了PhMgBr与PhCH_2COPh反应中2，6-二甲基对烯醇化反应和加成反应的影响，以及在CoCl_2存在下，2，4，6-Me_3C_6 H_2COCl与MeMgX和i-PrMgX反应生成α-二酮。并从电子转移机理对结果进行了讨论。
The effect of 2,6-dimethyl groups on enolization vs. addition in the reaction of PhMgBr with PhCH2COPh, and also the formation of α-diketone from 2,4,6-Me3C6H2COCl by the treatment with MeMgX and i-PrMgX in the presence of CoCl2, were studied. The results were discussed on the basis of electron-transfer mechanism.