Methylated molybdoplatinate--its unexpected ability to absorb methanol.

Methylated molybdoplatinate--its unexpected ability to absorb methanol.
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DOI:
10.1039/b915360h
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发表时间:
2010-01
影响因子:
4.9
通讯作者:
S. Ikegami;K. Kani;T. Ozeki;A. Yagasaki
S. Ikegami;K. Kani;T. Ozeki;A. Yagasaki
中科院分区:
化学2区
文献类型:
--
作者:
S. Ikegami;K. Kani;T. Ozeki;A. Yagasaki

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通过MoO(3)、H(2)Pt(OH)(6)和水溶液TBAOH以6:1:4的比例反应,得到了Anderson结构的甲基化铂钼酸盐,该盐吸收了大量的MeOH,超过其自重的三倍。
Methylated molybdoplatinate of the Anderson structure was obtained as a tetra-n-butylammonium (TBA) salt by reacting MoO(3), H(2)Pt(OH)(6), and aqueous TBAOH in a 6 : 1 : 4 ratio, which absorbed huge amounts of MeOH, more than three times as much as its own weight.