Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives
Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives
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DOI：
10.1021/ol203100u
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发表时间：
2012-01-06
期刊：
影响因子：
5.2
通讯作者：
Chatani, Naoto
中科院分区：
文献类型：
--
作者：
Ano, Yusuke;Tobisu, Mamoru;Chatani, Naoto
本文报道了钯催化芳香羧酸衍生物中C-H键的直接炔基化反应。使用8-氨基喹啉作为导向基团促进了电子多样范围的C（sp（2））-H键的炔基化。
The palladium-catalyzed direct alkynylation of C-H bonds in aromatic carboxylic acid derivatives is described. The use of 8-aminoquinoline as a directing group facilitates the alkynylation of an electronically diverse range of C(sp(2))-H bonds.