The large-Z Behavior of pseudorelativistic atoms

The large-Z Behavior of pseudorelativistic atoms
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伪相对论原子的大 Z 行为

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发表时间:
2004
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通讯作者:
T. O. Sorensen
T. O. Sorensen
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文献类型:
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作者:
T. O. Sorensen

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本文研究了具有相对论动能p2c2+m2c4−mc2的原子基态能量的大z行为。我们证明了在Z的第一阶能量与非相对论情况下相同,由(非相对论)托马斯-费米理论给出。为了使问题有意义,我们保持乘积Zα固定(这里α是索默菲尔德精细结构常数),并且小于或等于2∕π,这意味着当Z趋于无穷时,α趋于零。
In this paper we study the large-Z behavior of the ground state energy of atoms with electrons having relativistic kinetic energy p2c2+m2c4−mc2. We prove that to leading order in Z the energy is the same as in the nonrelativistic case, given by (nonrelativistic) Thomas–Fermi theory. For the problem to make sense, we keep the product Zα fixed (here α is Sommerfeld’s fine structure constant), and smaller than, or equal to, 2∕π, which means that as Z tends to infinity, α tends to zero.