New mimic of zeolite: heterometallic organic host framework accommodating inorganic cations
New mimic of zeolite: heterometallic organic host framework accommodating inorganic cations
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DOI:
10.1039/b927101e
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发表时间:
2010-01-01
影响因子:
4.9
通讯作者:
Zhang, Jian
中科院分区:
文献类型:
--
作者:
Chen, Yu-Biao;Kang, Yao;Zhang, Jian
Presented here is a heterometallic organic framework [Na-2(H2O)(10)](n)[CuZn4(mu(3)-OH)(4)(btec)(2)](n)center dot 2nH(2)O (1, btec = 1,2,4,5-benzenetetracarboxylate) that incorporates mixed Cu2+-Zn2+ oxide chains and accommodates Na+ cations as extraframework guest species; such a building mode is comparable to that of aluminosilicate zeolites where the porous framework combines two kinds of structural building units (such as [SiO4] and [AlO4]) and one kind of inorganic-templating cation.