Directed ortho metallation of deep cavity cavitands: functionalizing molecular concavity.
Directed ortho metallation of deep cavity cavitands: functionalizing molecular concavity.
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深腔空配体的定向邻位金属化：功能化分子凹面。
DOI：
10.1021/jo0513515
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发表时间：
2006
期刊：
影响因子：
--
通讯作者：
B. Gibb
中科院分区：
文献类型：
--
作者：
Z. Laughrey;B. Gibb
定向正交变换（DOM）过程已被用来功能化的标题腔1的腔和边缘。主办方的预先组织导致生产的产品范围大大减少。因此，虽然69种产物可能来自全官能化，但当用三种不同的烷基锂处理主体时，仅观察到12种。
Directed ortho metallation (DOM) processes have been used to functionalize the cavity and rim of title cavitand 1. The preorganization of the host resulted in a considerable reduction in the range of products produced. Thus, whereas sixty-nine products are possible from per-functionalization, only twelve were observed when the host was treated with three different alkyllithiums.