{[Cu(mtz)]3(CuI)}n: an unprecedented non-interpenetrated (12(3))(12(2).14)(3) network with triple-stranded helices.

{[Cu(mtz)]3(CuI)}n: an unprecedented non-interpenetrated (12(3))(12(2).14)(3) network with triple-stranded helices.
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DOI:
10.1021/ic0617341
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发表时间:
2007-01
影响因子:
4.6
通讯作者:
Xihe Huang;T. Sheng;Shenglin Xiang;R. Fu;Shengmin Hu;Ya-Min Li;Xintao Wu
Xihe Huang;T. Sheng;Shenglin Xiang;R. Fu;Shengmin Hu;Ya-Min Li;Xintao Wu
中科院分区:
化学2区
文献类型:
--
作者:
Xihe Huang;T. Sheng;Shenglin Xiang;R. Fu;Shengmin Hu;Ya-Min Li;Xintao Wu

文献摘要

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在水热条件下合成了一种具有三股螺旋结构的配合物{[Cu(mtz)]3(CuI)}n。该配合物具有前所未有的非互穿(12(3))(12(2).14)3网络,这是迄今为止报道的阿基米德网络最小环的最大gon值的第一个例子。
A complex with triple-stranded helices, {[Cu(mtz)]3(CuI)}n, was obtained under hydrothermal conditions. The complex possesses an unprecedented non-interpenetrated (12(3))(12(2).14)3 network, which represents the first example of the largest gon value of the smallest ring for the Archimedean net reported so far.