Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes.
Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes.
复制标题
DOI：
10.1021/ja7108272
复制
发表时间：
2008-02
影响因子：
15
通讯作者：
Li‐Biao Han;Y. Ono;S. Shimada
中科院分区：
文献类型：
--
作者：
Li‐Biao Han;Y. Ono;S. Shimada
在二价钯催化剂存在下，端炔与膦酸酯发生脱氢顺式双磷酸化反应，选择性地得到（Z）-双磷酰基-1-烯烃。
Dehydrogenative cis double phosphorylation of terminal alkynes with H-phosphonate took place efficiently in the presence of a divalent palladium catalyst to afford (Z)-bisphosphoryl-1-alkenes selectively.