Highly effective discrimination of catecholamine derivatives via FRET-on/off processes induced by the intermolecular assembly with two fluorescence sensors

Highly effective discrimination of catecholamine derivatives via FRET-on/off processes induced by the intermolecular assembly with two fluorescence sensors
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DOI:
10.1039/c3cc45077e
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Tomapatanaget, Boosayarat
Tomapatanaget, Boosayarat
中科院分区:
化学2区
文献类型:
--
作者:
Chaicham, Anusak;Sahasithiwat, Somboon;Tomapatanaget, Boosayarat

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我们自豪地提出了基于两个荧光传感器的分子间组装络合物和合适的儿茶酚胺作为客体连接物的新型传感器体系,通过传感器的硼酸和乙醛部分分别与儿茶酚胺的二醇基和胺基反应。由组装引起的FRET-ON/OFF可以区分儿茶酚胺的结构相似性。
We proudly presented the novel sensor system based on intermolecular assembled complexes of two fluorescence sensors and a suitable catecholamine acting as a guest linker by the reaction between boronic acid and aldehyde moieties of the sensors with the diol and amine units of catecholamines, respectively. The FRET-on/off induced by the assembly could discriminate structural similarity of catecholamines.