Syntheses and structures of [M(CO)5{B2H4.cntdot.2P(CH3)3}] and [M(CO)4{B2H4.cntdot.2P(CH3)3}] (M = chromium, molybdenum, tungsten)

Syntheses and structures of [M(CO)5{B2H4.cntdot.2P(CH3)3}] and [M(CO)4{B2H4.cntdot.2P(CH3)3}] (M = chromium, molybdenum, tungsten)
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[M(CO)5{B2H4.cntdot.2P(CH3)3}] 和 [M(CO)4{B2H4.cntdot.2P(CH3)3}] 的合成和结构(M = 铬、钼、钨)

DOI:
10.1021/ic00030a028
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发表时间:
1992
影响因子:
4.6
通讯作者:
H. Ogino
H. Ogino
中科院分区:
化学2区
文献类型:
--
作者:
Kinji Katoh;M. Shimoi;H. Ogino

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M(CO)6(M=Cr,Mo,W)与B 2 H4.2 P(CH 3)3(1)的光化学反应,得到两种新的配合物:0 [M(CO)5 -{B 2 H4.2 P(CH 3)3 }](2)(M=Cr,W)和[M(CO)4 {B 2 H4.2 P(CH 3)3 }](3)(M=Cr,Mo,W).两种配合物的结构均通过光谱测量和X射线结构分析表征
Photochemical reactions of M(CO) 6 (M=Cr, Mo, W) with B 2 H 4 .2P(CH 3 ) 3 (1) gave two types of new complexes:0 [M(CO) 5 -{B 2 H 4 .2P(CH 3 ) 3 }] (2) (M=Cr, W) and [M(CO) 4 {B 2 H 4 .2P(CH 3 ) 3 }] (3) (M=Cr, Mo, W). Structures of both types of complexes were characterized by spectroscopic measurements as well as X-ray structure analyses