Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size.
Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size.
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DOI：
10.1039/b718260k
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发表时间：
2008-02
影响因子：
4.9
通讯作者：
Alice Merca;H. Bögge;M. Schmidtmann;Yunshan Zhou;Erhard T. K. Haupt;M. Khaled Sarker;C. Hill;A. Müller
中科院分区：
文献类型：
--
作者：
Alice Merca;H. Bögge;M. Schmidtmann;Yunshan Zhou;Erhard T. K. Haupt;M. Khaled Sarker;C. Hill;A. Müller
根据X射线晶体学研究，独特的氧化钼基亲核多孔胶囊/人工细胞[{（MoVI）MoVI 5 O 21（H2O）6}12{MoV 2 O 4（SO 4）30}]72-将[Al（H2O）6]3+络合物捕获在孔上方，同时通过氢键与后者相互作用;这得到了水溶液中胶囊与水合Al 3+阳离子相互作用的27 Al NMR研究的支持。
The unique molybdenum oxide-based nucleophilic porous capsule/artificial cell [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4(SO4)30}]72-, according to an X-ray crystallographic study, traps [Al(H2O)6]3+ complexes above the pores while interacting with the latter via hydrogen bonds; this is supported by 27Al NMR studies of the interaction of the capsule with hydrated Al3+ cations in aqueous solution.