Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation
Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation
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DOI：
10.1039/b700140a
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发表时间：
2007-06-14
影响因子：
4.9
通讯作者：
Kondo, Yoshinori
中科院分区：
文献类型：
--
作者：
Ueno, Masahiro;Yonemoto, Misato;Kondo, Yoshinori
以Et_3SiH/cat. t-Bu-P_4为催化剂，进行了一种新型的亲核试剂的去质子化芳基化反应，并以醇和丙二酸酯为亲核试剂，完成了芳基氟的强SNAr反应.
A novel type of deprotonative arylation of nucleophiles was conducted using Et3SiH/cat. t-Bu-P4 and the powerful SNAr reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles.