Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation
Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation
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DOI：
10.1039/c1cc13993b
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
de Visser, Sam P.
中科院分区：
文献类型：
--
作者：
Latifi, Reza;Tahsini, Laleh;de Visser, Sam P.
探讨了Ni(II)-超氧配合物在C-H键活化、芳香羟基化和杂原子氧化反应中的反应活性的密度泛函理论计算；Ni(II)-超氧配合物能够与弱C-H键和PPh3的底物反应。
Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(II)-superoxo complex is able to react with substrates with weak C-H bonds and PPh3.