Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer
Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer
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DOI：
10.1063/1.1755833
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发表时间：
2004-05
影响因子：
4
通讯作者：
S. Uchida;J. Xue;Barry P Rand;S. Forrest
中科院分区：
文献类型：
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作者：
S. Uchida;J. Xue;Barry P Rand;S. Forrest
描述了一种具有真空共沉积供体-受体铜酞菁 (CuPc):C60 混合层的高效有机太阳能电池。采用氧化铟锡/330 A CuPc:C60(1:1)/100 A C60/75 A 2,9-二甲基-4,7-二苯基-1,10-菲咯啉/Ag结构的器件，串联电阻仅为RS=0.25 Ω cm2，在+1 V正向偏压下电流密度为∼1 A/cm2，整流比为 106 at ±1 V。在模拟太阳光照下，短路电流密度随着光强度线性增加，最高可达 2.4 个太阳光。 0.3个太阳时（AM1.5G模拟太阳光谱）最大功率转换效率为ηP=(3.6±0.2)%，1个太阳时ηP=(3.5±0.2)%。尽管填充因子随着强度的增加而降低，但在 2.4 个太阳强度下观察到高达 ηP=(3.3±0.2)% 的功率效率。
An efficient organic solar cell with a vacuum codeposited donor–acceptor copper phthalocyanine (CuPc):C60 mixed layer is described. A device with a structure of indium tin oxide/330 A CuPc:C60(1:1)/100 A C60/75 A 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline/Ag has a series resistance of only RS=0.25 Ω cm2, resulting in a current density of ∼1 A/cm2 at a forward bias of +1 V, and a rectification ratio of 106 at ±1 V. Under simulated solar illumination, the short circuit current density increases linearly with light intensity up to 2.4 suns. The maximum power conversion efficiency is ηP=(3.6±0.2)% at 0.3 suns (AM1.5G simulated solar spectrum) and ηP=(3.5±0.2)% at 1 sun. Although the fill factor decreases with increasing intensity, a power efficiency as high as ηP=(3.3±0.2)% is observed at 2.4 suns intensity.