Bifunctional Supertetrahedral Chalcogenolate Cluster-based Assembly Materials Constructed by Photoactive Ligand
Bifunctional Supertetrahedral Chalcogenolate Cluster-based Assembly Materials Constructed by Photoactive Ligand
复制标题
光活性配体构建的双功能超四面体硫属醇盐簇基组装材料
作者：
Yanling Li;Pengtao Sheng;Fu-An Li;Ruibing Bai;Xianming Gao;Yongjun Han
超四面体硫代酚酸酯簇（SCCs）与多功能有机连接体的组装可以形成可调的结构和协同性能。成功合成了两种由三角形发色团配体三（4-吡啶基苯基）胺构成的scam - 1,2组装材料。sccam在低温（83 K）下表现出异常长寿命的余辉，并具有有效的光催化降解水中有机染料的活性。
The assembly of supertetrahedral chalcogenolate clusters (SCCs) and multifunctional organic linkers could lead to the formation of tunable structures and synergistic properties. Two SCC-based assembled materials (SCCAM-1, 2) constructed by a triangular chromophore ligand tri(4-pyridylphenyl)amine were successfully synthesized and characterized. The SCCAMs demonstrate unusually long-lived afterglow at low temperatures (83 K) and efficient activities for the photocatalytic degradation of organic dye in water.