Halogenated Bis(methylthio)tetrathiafulvalenes as a Unique Donor System
Halogenated Bis(methylthio)tetrathiafulvalenes as a Unique Donor System
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卤化双（甲硫基）四硫富瓦烯作为独特的供体系统
DOI：
10.1246/cl.1997.599
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发表时间：
1997
影响因子：
1.6
通讯作者：
Takehiko Mori
中科院分区：
文献类型：
--
作者：
M. Iyoda;Y. Kuwatani;K. Hara;E. Ogura;Hironori Suzuki;Hitoshi Ito;Takehiko Mori
双(甲硫基)四硫富瓦烯(BMT-TTF)的氯化、溴化和碘化反应主要生成二卤代产物(BMT-TTFX2)和少量一卤代衍生物(BMT-TTFX)。测定了BMT-TTFBr2和BMT-TTFBr2·i3的分子结构，并测定了BMT-TTFX2的CT-络合物和自由基盐的电导。
Chlorination, bromination and iodination of bis(methylthio)tetrathiafulvalene (BMT-TTF) produced mainly the dihalogenated products (BMT-TTFX2) with small amounts of the monohalogenated derivatives (BMT-TTFX). The molecular structures of BMT-TTFBr2 and BMT-TTFBr2•I3 have been determined, and the conductivities of CT-complexes and radical salts derived from BMT-TTFX2 have been measured.