Cross-linking dendrimers with allyl ether end-groups using the ring-closing metathesis reaction
Cross-linking dendrimers with allyl ether end-groups using the ring-closing metathesis reaction
复制标题
DOI：
10.1021/jo049368v
复制
发表时间：
2004-10-15
影响因子：
3.6
通讯作者：
Zimmerman, SC
中科院分区：
文献类型：
--
作者：
Elmer, SL;Zimmerman, SC
A third generation Frechet-type dendrimer containing 24 allyl ether end-groups was synthesized, crosslinked using the ring-closing metathesis (RCM) reaction, and the core was removed hydrolytically without significant fragmentation. The results are analogous to those previously reported for homoallyl ether dendrimers (Wendland, M. S.; Zimmerman, S. C. J. Am. Chem. Soc. 1999,121,1389-1390) suggesting that the less readily available homoallyl ether dendrimers can be replaced by their allyl ethers analogues in a range of applications.
