Amphiphilic Organocatalyst for Schotten-Baumann-Type Tosylation of Alcohols under Organic Solvent Free Condition
Amphiphilic Organocatalyst for Schotten-Baumann-Type Tosylation of Alcohols under Organic Solvent Free Condition
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DOI：
10.1021/ol900125y
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发表时间：
2009-04-16
期刊：
影响因子：
5.2
通讯作者：
Matsubara, Seijiro
中科院分区：
文献类型：
--
作者：
Asano, Keisuke;Matsubara, Seijiro
以N-十六烷基咪唑为催化剂，在含K_2CO_3的水溶液中有效地进行了伯醇与对甲苯磺酰氯的对甲苯磺酰化反应。
A Tosylation of primary alcohol with tosyl chloride was performed effectively with an N-hexadecylimidazole catalyst in water containing K2CO3aggregation of the catalyst carrying a hydrophobic methylene chain worked as a substitute for organic solvent.