Microwave Assisted Synthesis of Organic-Inorganic Polymer Hybrids
Microwave Assisted Synthesis of Organic-Inorganic Polymer Hybrids
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DOI：
10.1007/s00289-005-0436-8
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发表时间：
2005-09
期刊：
影响因子：
3.2
通讯作者：
K. Adachi;T. Iwamura;Y. Chujo
中科院分区：
文献类型：
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作者：
K. Adachi;T. Iwamura;Y. Chujo
利用微波加热的方法制备了聚环氧乙烷和聚乙烯吡咯烷酮等有机聚合物的有机-无机杂化材料。在500 W、2.45 GHz的微波辐射下，聚合物杂化材料的形成速度加快.所得聚合物杂化物是光学透明的，并且没有观察到相分离。从所得聚合物杂化物的SEM图像和红外光谱，微波加热合成的聚合物杂化物的组成和性能被发现与常规加热合成的聚合物杂化物基本相同。
Organic-inorganic polymer hybrids from various organic polymers such as poly(ethylene oxide) and poly(N-vinylpyrrolidone) were prepared with the assistance of microwave heating. With the 500 W, 2.45 GHz of microwave irradiation, the formation of polymer hybrids was accelerated. The obtained polymer hybrids were optically transparent and no phase separation was observed. From the SEM images and IR spectra of the obtained polymer hybrids, the composition and the properties of the polymer hybrids synthesized with microwave heating were found to be mostly the same as that synthesized with conventional heating.