Synthesis of fulvene-containing boron complexes with aggregation-induced emission and mechanochromic luminescence.
Synthesis of fulvene-containing boron complexes with aggregation-induced emission and mechanochromic luminescence.
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DOI：
10.1039/d0cc05757f
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发表时间：
2020-11
影响因子：
4.9
通讯作者：
Cai-Xin Yan;Qian-Qian Lin-Qian;Sha Li;Cheng Wu;Yan-An Li;Jianzhong Fan;Jianping Ma;Y. Geng;Yu‐Bin Dong
中科院分区：
文献类型：
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作者：
Cai-Xin Yan;Qian-Qian Lin-Qian;Sha Li;Cheng Wu;Yan-An Li;Jianzhong Fan;Jianping Ma;Y. Geng;Yu‐Bin Dong
以氟烯二酮酸二氟化硼（FDB）为有机受体，合成了两个含氟烯基序的配合物。两种二氟硼配合物均具有聚集诱导发射（AIE）特性和细胞示踪功能，具有良好的生物相容性。通过对BL2的合成、分离和表征，实现了机械致色发光。
Two donor-acceptor motif fulvene-containing boron complexes were synthesized with fulvene diketonate boron difluoride (FDB) as the organic acceptor. Both difluoroboron complexes present aggregation-induced emission (AIE) properties and cell tracing function with excellent biocompatibility. And mechanochromic luminescence has been accomplished by the synthesis, isolation and characterization of BL2.