Interfaces of ionic liquids.
Interfaces of ionic liquids.
复制标题
离子液体的界面。
DOI：
10.1039/c2cp90031a
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
F. Endres
中科院分区：
文献类型：
--
作者：
F. Endres
近15年来，离子液体在世界范围内受到了前所未有的关注，每年的出版物数量都在不断增加。1997年，该领域发表的论文不到50篇，离子液体在当时绝对是外来的，但仅仅5年后的2002年，已经发表了500多篇论文。2011年，超过4000篇论文涉及这类液体，并且仍有一个不断增长的全球社区使用这些液体进行实验和理论研究。值得注意的是，中国在这一领域发展迅速，2011年仅中国团体就发表了1200多篇论文。在最近的4年里，人们发现离子液体显示出有趣的界面化学，这些部分不寻常的观察是这个主题的动机。来自澳大利亚纽卡斯尔大学的罗布·阿特金（Rob Atkin）是第一批能够用原子力显微镜证明离子液体在固体表面形成几个非常牢固的溶剂化层的人。1他的结果得到了Mezger等人的证实。2从那时起，人们对离子液体的界面化学越来越感兴趣。Seddon等人发现离子液体原则上可以蒸馏3，Heintz等人是第一个通过红外光谱研究蒸馏离子液体的人。4与此同时，Souda 5和Steinruelck等人6表明，离子液体的多层膜可以在真空条件下通过蒸发制成，而Steinruelck的观点（DOI：10.1039/c2cp 24087 d）在本主题期刊中很好地总结了通过角分辨X射线光电子能谱获得的关键结果。超高真空蒸发是制备无杂质离子液体的一种非常有前途的方法，Behm等人通过温度依赖性UHV-STM展示了离子液体单层的分子分辨STM图像。7 Kornyshev等人，8 Fedorov 9和Bazant等人10在一系列理论论文中表明，电极和离子液体之间的界面
During the recent 15 years ionic liquids have experienced an unprecedented worldwide rising interest which is manifested in a still increasing number of publications every year. In 1997 there were less than 50 papers published in the field, and ionic liquids were definitely exotic at that time, but just 5 years later in 2002 already more than 500 papers were published. In 2011 more than 4000 papers dealt with this class of liquids and there is a still growing worldwide community doing experiments and theory with these liquids. It is remarkable that China has developed rapidly in this field, and in 2011 more than 1200 papers were published by Chinese groups alone. During the recent maybe 4 years it has been found that ionic liquids show an interesting interfacial chemistry, and these in part unusual observations were the motivation for this Themed Issue. Rob Atkin from Newcastle University, Australia, was among the first who could show with Atomic Force Microscopy that ionic liquids form several remarkably strongly adhering solvation layers on solid surfaces. 1 His results were confirmed by Mezger et al. 2 and from then on a rising interest in the interfacial chemistry of ionic liquids could be observed. Seddon et al. found that ionic liquids can in principle be distilled3 and Heintz et al. were the first ones who studied distilled ionic liquids by means of IR spectroscopy. 4 In parallel, Souda5 and SteinruĻck et al. 6 showed that ultrathin layers of ionic liquids can be made by evaporation under the conditions of an ultrahigh vacuum and the Perspective from SteinruĻck (DOI: 10.1039/c2cp24087d) in this Themed Issue summarizes well the key results obtained by angle resolved X-ray photoelectron spectroscopy. UHV evaporation is quite a promising way to make impurity free ionic liquids and Behm et al. showed molecularly resolved STM images of an ionic liquid monolayer by temperature dependent UHV-STM. 7 Kornyshev et al., 8 Fedorov9 and Bazant et al. 10 showed in a series of theory papers that the interface between an electrode and an ionic liquid
影响因子：
8.6
作者：
Bazant, Martin Z.;Storey, Brian D.;Kornyshev, Alexei A.
通讯作者：
Kornyshev, Alexei A.