Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks.
Coordination distortion induced water adsorption in hydrophobic flexible metal-organic frameworks.
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DOI：
10.1039/d0cc03772a
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发表时间：
2020-07
影响因子：
4.9
通讯作者：
Y. Kamakura;Arata Hikawa;Hirofumi Yoshikawa;W. Kosaka;H. Miyasaka;D. Tanaka
中科院分区：
文献类型：
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作者：
Y. Kamakura;Arata Hikawa;Hirofumi Yoshikawa;W. Kosaka;H. Miyasaka;D. Tanaka
在此，我们合成了四个等结构的柔性间指疏水金属-有机框架，它们的不同之处在于它们的中心金属离子。吸附性能与金属种类有关，这是由金属离子周围的配位畸变引起的。
Herein, we synthesized four isostructural flexible interdigitated hydrophobic metal-organic frameworks that differ only in their central metal ion. The water-adsorption properties are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.