Introduction to Stereochemistry and Conformational Analysis

Introduction to Stereochemistry and Conformational Analysis
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立体化学和构象分析简介

DOI:
10.5860/choice.29-4532
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发表时间:
1991
期刊:
影响因子:
2.1
通讯作者:
E. Juaristi
E. Juaristi
中科院分区:
化学3区
文献类型:
--
作者:
E. Juaristi

文献摘要

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手性。绝对配置。立体化学和构象描述符。手性分子的手性光学特性。有机反应的立体化学。前手性。不对称有机合成:原理。对映体纯度。外消旋体的解析。通过手性催化剂的不对称合成。手性底物的不对称合成。非手性底物和手性试剂之间的不对称反应。立体化学控制的各种方法。无环和环烷烃的构象分析。动态核磁共振波谱在构象分析中的应用。杂环的构象分析。异头效应。吸引力和排斥性的粗俗效应。作者索引。主题索引。
Chirality. Absolute Configuration. Stereochemical and Conformational Descriptors. Chiroptic Properties in Chiral Molecules. Stereochemistry of Organic Reactions. Prochirality. Asymmetric Organic Synthesis: Principles. Enantiomeric Purity. Resolution of Racemates. Asymmetric Synthesis via a Chiral Catalyst. Asymmetric Syntheses with Chiral Substrates. Asymmetric Reactions Between Achiral Substrates and Chiral Reagents. Miscellaneous Methods for the Control of Stereochemistry. The Conformational Analysis of Acyclic and Cycloalkanes. Applications of Dynamic NMR Spectroscopy in Conformational Analysis. Conformational Analysis of Heterocycles. The Anomeric Effect. The Attractive and Repulsive Gauche Effects. Author Index. Subject Index.