Mass spectrometric detection of enantioselectivity in three-component complexation, copper(II)-chiral tetradentate ligand-free amino acid in solution
Mass spectrometric detection of enantioselectivity in three-component complexation, copper(II)-chiral tetradentate ligand-free amino acid in solution
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DOI：
10.1039/c9cc07231d
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发表时间：
2020-01-04
影响因子：
4.9
通讯作者：
Shizuma, Motohiro
中科院分区：
文献类型：
--
作者：
Nakakoji, Takashi;Sato, Hirofumi;Shizuma, Motohiro
采用电喷雾电离质谱法结合氘标记的准对映体，在短时间内定量评价了游离氨基酸作为铜（II）配合物的第二配体与一种新型手性四齿配体的对映选择性配位。
By using electrospray ionization mass spectrometry coupled with the use of deuterium-labelled quasienantiomers, enantioselective coordination of a free amino acid as the second ligand of a copper(II) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time.