Quasi-thermoneutral P → B interactions within Di- and tri-phosphine boranes

Quasi-thermoneutral P → B interactions within Di- and tri-phosphine boranes
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DOI:
10.1021/ic7006556
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发表时间:
2007-06-25
影响因子:
4.6
通讯作者:
Bourissou, Didier
Bourissou, Didier
中科院分区:
化学2区
文献类型:
--
作者:
Bontemps, Sebastien;Bouhadir, Ghenwa;Bourissou, Didier

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光谱、结构和理论证据都提供了开放(无分子内P -> B相互作用)和封闭(有分子内P -> B相互作用)形式的二-和三-膦硼烷[o-(iPr(2)P)C6 H4](2)BPh(2)和[o-(iPr(2)P)C6 H4](3)B(3)。
Spectroscopic, structural, and theoretical evidence is provided for both open (no intramolecular P -> B interaction) and closed (with intramolecular P -> B interaction) forms of the di- and tri-phosphine boranes [o-(iPr(2)P)C6H4](2)BPh (2) and [o-(iPr(2)P)C6H4](3)B (3).