Pentaamminechlorogallium(III) dichloride
Pentaamminechlorogallium(III) dichloride
复制标题
二氯化五氨合氯化镓(III)
DOI：
10.1107/s1600536807003388
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发表时间：
2007
影响因子：
0.9
通讯作者：
C. Yokoyama
中科院分区：
文献类型：
--
作者：
H. Yamane;Y. Mikawa;C. Yokoyama
标题化合物[Ga（NH 3）5Cl] Cl 2的晶体由氯化1-丁基-3-甲基咪唑鎓和GaCl 3制备。晶体结构与[Al（NH3）5Cl] Cl 2和[M（NH3）5Cl] Cl 2系列的其他成员是同型的，M = Cr，Co，Rh，Ir，Ru或Os。它由离散的阳离子[Ga（NH3）5Cl]2+八面体和Cl−阴离子组成，排列在与K2 PtCl 6结构类型相关的基序中。在阳离子中，Ga原子、一个Cl原子和三个N原子位于镜面上。
Crystals of the title compound, [Ga(NH3)5Cl]Cl2, were prepared from 1-butyl-3-methylimidazolium chloride and GaCl3. The crystal structure is isotypic with [Al(NH3)5Cl]Cl2 and other members of the series [M(NH3)5Cl]Cl2, with M = Cr, Co, Rh, Ir, Ru or Os. It consists of discrete cationic [Ga(NH3)5Cl]2+ octahedra and Cl− anions arranged in motifs related to the K2PtCl6 structure type. In the cation, the Ga atom, one Cl atom and three N atoms are located on a mirror plane.